https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Structural and aggregate analyses of (Li salt + glyme) mixtures: the complex nature of solvate ionic liquids https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:21264 q) functions derived from diffraction and scattering data (HEXRD and SAXS/WAXS). The competition between the glyme molecules and the salt anions for the coordination to the lithium cations is quantified by comprehensive aggregate analyses. Lithium-glyme solvates are dominant in the lithium bis(trifluoromethylsulfonyl)imide systems and much less so in systems based on the other two salts. The aggregation studies also emphasize the existence of complex coordination patterns between the different species (cations, anions, glyme molecules) present in the studied fluid media. The analysis of such complex behavior is extended to the conformational landscape of the anions and glyme molecules and to the dynamics (solvate diffusion) of the bis(trifluoromethylsulfonyl)imide plus triglyme system.]]> Wed 11 Apr 2018 16:08:15 AEST ]]> Li⁺ local structure in li-tetraglyme solvate ionic liquid revealed by neutron total scattering experiments with the ⁶/⁷Li Isotopic Substitution Technique (letter) https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:25095 Sat 24 Mar 2018 07:15:03 AEDT ]]>